Electrocatalytic activity and stability of La1-xCaxCoO3 perovskite-type oxides in alkaline medium
Identifieur interne : 000217 ( France/Analysis ); précédent : 000216; suivant : 000218Electrocatalytic activity and stability of La1-xCaxCoO3 perovskite-type oxides in alkaline medium
Auteurs : Abdelkrim Kahoul [Algérie] ; Abderrezak Hammouche [Allemagne] ; Gérard Poillerat [France] ; Rik W. De Doncker [Allemagne]Source :
- Catalysis today [ 0920-5861 ] ; 2004.
Descripteurs français
- Pascal (Inist)
- Wicri :
- topic : Oxyde.
English descriptors
- KwdEn :
Abstract
Electrocatalytic activity versus oxygen evolution of perovskite-type cobalt oxide (La1-xCaxCoO3, with x = 0.0, 0.2, 0.4 and 0.6) was evaluated by potentiostatic polarization technique, as a function of the electrode chemical composition. Stability of the electrode material in alkaline medium under stressing galvanostatic conditions was investigated. Highly sensitive differential pulse adsorptive stripping voltammetry (DPAdSV) technique was successfully applied for determination of traces of dissolved cobalt in the electrolyte solution. The results point out the optimum electrode activity and stability of the x = 0.4 composition.
Affiliations:
- Algérie, Allemagne, France
- Alsace (région administrative), District de Cologne, Grand Est, Rhénanie-du-Nord-Westphalie
- Aix-la-Chapelle, Strasbourg
Links toward previous steps (curation, corpus...)
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- to stream Main, to step Merge: 000A22
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Pascal:04-0235916Le document en format XML
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Ca<sub>x</sub>
CoO<sub>3</sub>
perovskite-type oxides in alkaline medium</title>
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<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a">Electrocatalytic activity and stability of La<sub>1-x</sub>
Ca<sub>x</sub>
CoO<sub>3</sub>
perovskite-type oxides in alkaline medium</title>
<author><name sortKey="Kahoul, Abdelkrim" sort="Kahoul, Abdelkrim" uniqKey="Kahoul A" first="Abdelkrim" last="Kahoul">Abdelkrim Kahoul</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Laboratory for Energetics and Electrochemistry of Solids, Department of Processes Engineering E Abbas University of Setif</s1>
<s2>19000 Setif</s2>
<s3>DZA</s3>
<sZ>1 aut.</sZ>
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<country>Algérie</country>
<wicri:noRegion>19000 Setif</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Hammouche, Abderrezak" sort="Hammouche, Abderrezak" uniqKey="Hammouche A" first="Abderrezak" last="Hammouche">Abderrezak Hammouche</name>
<affiliation wicri:level="3"><inist:fA14 i1="02"><s1>Institute for Power Electronics and Electrical Drives, Aachen University of Technology, Jägerstr. 17-19</s1>
<s2>52066 Aachen</s2>
<s3>DEU</s3>
<sZ>2 aut.</sZ>
<sZ>4 aut.</sZ>
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<author><name sortKey="Poillerat, Gerard" sort="Poillerat, Gerard" uniqKey="Poillerat G" first="Gérard" last="Poillerat">Gérard Poillerat</name>
<affiliation wicri:level="3"><inist:fA14 i1="03"><s1>Laboratoire d'Electrochimie et Chimie Physique du Corps Solide, UMR CNRS/ULP 7512, 4 Rue Blaise Pascal</s1>
<s2>67000 Strasbourg</s2>
<s3>FRA</s3>
<sZ>3 aut.</sZ>
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<country>France</country>
<placeName><region type="region" nuts="2">Grand Est</region>
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<settlement type="city">Strasbourg</settlement>
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<affiliation wicri:level="3"><inist:fA14 i1="02"><s1>Institute for Power Electronics and Electrical Drives, Aachen University of Technology, Jägerstr. 17-19</s1>
<s2>52066 Aachen</s2>
<s3>DEU</s3>
<sZ>2 aut.</sZ>
<sZ>4 aut.</sZ>
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<country>Allemagne</country>
<placeName><region type="land" nuts="1">Rhénanie-du-Nord-Westphalie</region>
<region type="district" nuts="2">District de Cologne</region>
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<series><title level="j" type="main">Catalysis today</title>
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<idno type="ISSN">0920-5861</idno>
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<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Cobalt oxide</term>
<term>Oxides</term>
<term>Perovskite</term>
<term>Stability</term>
<term>Voltammetry</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Stabilité</term>
<term>Perovskite</term>
<term>Oxyde</term>
<term>Cobalt oxyde</term>
<term>Voltammétrie</term>
</keywords>
<keywords scheme="Wicri" type="topic" xml:lang="fr"><term>Oxyde</term>
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<front><div type="abstract" xml:lang="en">Electrocatalytic activity versus oxygen evolution of perovskite-type cobalt oxide (La<sub>1-x</sub>
Ca<sub>x</sub>
CoO<sub>3</sub>
, with x = 0.0, 0.2, 0.4 and 0.6) was evaluated by potentiostatic polarization technique, as a function of the electrode chemical composition. Stability of the electrode material in alkaline medium under stressing galvanostatic conditions was investigated. Highly sensitive differential pulse adsorptive stripping voltammetry (DPAdSV) technique was successfully applied for determination of traces of dissolved cobalt in the electrolyte solution. The results point out the optimum electrode activity and stability of the x = 0.4 composition.</div>
</front>
</TEI>
<affiliations><list><country><li>Algérie</li>
<li>Allemagne</li>
<li>France</li>
</country>
<region><li>Alsace (région administrative)</li>
<li>District de Cologne</li>
<li>Grand Est</li>
<li>Rhénanie-du-Nord-Westphalie</li>
</region>
<settlement><li>Aix-la-Chapelle</li>
<li>Strasbourg</li>
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<name sortKey="De Doncker, Rik W" sort="De Doncker, Rik W" uniqKey="De Doncker R" first="Rik W." last="De Doncker">Rik W. De Doncker</name>
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<country name="France"><region name="Grand Est"><name sortKey="Poillerat, Gerard" sort="Poillerat, Gerard" uniqKey="Poillerat G" first="Gérard" last="Poillerat">Gérard Poillerat</name>
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